"How could Substack improve this situation for technical writers?"
How about this: don't run a dumb as rocks Web Application Firewall on an endpoint where people are editing articles that could be about any topic, including discussing the kind of strings that might trigger a dumb as rocks WAF.
This is like when forums about web development implement XSS filters that prevent their members from talking about XSS!
Learn to escape content properly instead.
I'm in the position where I have to run a WAF to pass security certifications. The only open source WAFs are modsecurity and it's beta successor, coraza. These things are dumb, they just use OWASP's coreruleset which is a big pile of unreadable garbage.